Color harmonies are useful starting points, but they solve different visual problems. Complementary colors create a stronger contrast; analogous colors usually feel closer and calmer because their hues sit near each other.
Compare one color in two systems
Take a blue swatch from an image. A complementary partner may be orange, which is useful for a callout or focal object. An analogous group may move through blue, cyan and violet, which can support a quieter background. Neither scheme guarantees readable text: test lightness and contrast separately.
Build a hierarchy, not a rainbow
Choose a main color, a supporting color and a small accent. If every element uses the brightest hue, the eye has nowhere to settle. The NexTools Color Palette tool shows complementary, analogous and other matching schemes for a selected swatch. Try both on one real composition and compare which message becomes easier to see.
Keep a record of the final color values. The best harmony is the one that works with your subject, audience and output format, not the one whose swatches look most symmetrical in a generator.